17615
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17615
Fluka
(Bromomethyl)chlorodimethylsilane
purum, ≥96.0% (GC)
| Synonym: | (Bromomethyl)dimethylchlorosilane, BMDMCS |
| CAS Number: | 16532-02-8 |
| Linear Formula: | BrCH2Si(CH3)2Cl |
| Molecular Weight: | 187.54 |
| Beilstein Registry Number: | 1071201 |
| EC Number: | 240-601-7 |
| MDL number: | MFCD00000503 |
Description
| Other Notes | Derivatizing agent for electron capture gas chromatography 1,2; Allylic bromomethylsilyl ethers allow the stereoselective introduction of a cis hydroxymethyl or methyl group via radical cyclization 3 |
Properties
| vapor density | >1 (vs air) |
| grade | purum |
| assay | ≥96.0% (GC) |
| refractive index | n |
| n | |
| bp | 130 °C/740 mmHg(lit.) |
| density | 1.375 g/mL at 25 °C(lit.) |
Safety
| Personal Protective Equipment | Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
| Hazard Codes | C |
| Risk Statements | 10-34 |
| Safety Statements | 26-36/37/39-45 |
| RIDADR | UN2986 8/PG 2 |
| WGK Germany | 3 |
| Flash Point(F) | 105.8 °F |
| Flash Point(C) | 41 °C |
References
| Cited Reference | 1. C.F. Poole, A. Zlatkis J. Chromatogr. Sci. 17, 115, (1979) |
| 2. J. Heberle, G. Simchen Silylating Agents, 2nd ed. Buchs , (1995) | |
| 3. G. Stork, R. Mah Tetrahedron Lett. 30, 3609, (1989) | |
| Beilstein | Beil. 4,IV,4024 |
| reference | Aldrich MSDS 1, 264:D / Corp MSDS 1 (1), 548:B / FT-IR 1 (2), 1106:A / FT-IR 2 (3), 4355:B / FT-NMR 1 (3), 647:B / RegBook 1 (2), 2961:F / Structure Index 1, 468:E:7 / Vapor Phase 3, 1634:C |
